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HydroDeSulphuriser (under)performance investigation

-van der Grift Catalyst Specialist
HydroDeSulphuriser (under)performance investigation


 

 

ULSD operation environment

In today’s 10 ppm Ultra-Low Sulphur Diesel world, the HydroTreater (HT) or HydroDeSulphurisation (HDS) unit has become an upgrader with an appreciable contribution to the Refinery Margin. Some of them were recently built, some of them are decades old and have been revamped to the new specifications, but the incentive to improve on their bottom line will not disappear. Underperformance is costly and effective troubleshooting is required to quickly recover the lost margin in a sustainable manner.
 

Unit health check - optimal catalyst performance 

Unless a problem has clearly manifested itself – such as a pressure drop issue – it is wise to carry out a performance or health check every 1-2 years. Such a health check evaluates the unit at various levels:
1.Daily operation
2.Reactor Internals
3.Catalyst cycle & feedstock optimisation

Findings can also be input for longer term optimisation, such as the next cycle catalyst selection and/or future revamp options.

Operational review

A check on daily operation focusses on the following 4 aspects: 
1.Review of unit planned and un-planned down-time can bring up options to improve unit availability. 
2.Review of the unit energy use by checking the heat-exchanger duties, furnace efficiency and steam use.
3.Yield check: this can be improved if the separation of slops in the work-up section is poor. For example, reducing give-away on Flash Point is a way to boost product yield.
4.For the unit integrity its water balance needs to be reviewed to ensure that the ammonium salts that are produced in the reactor are continuously being removed.
 

Reactor utilisation

The catalytic reactions in the reactor are the heart of the HDS. The catalyst requires the optimum temperature profile and uniform trickle flow conditions during its life cycle and the reactor internals need to safeguard this. A review of the tray hydraulics using, among others, quench test data can ensure this.
Secondly, a check of the loading diagram is required to assess maximum catalyst activity as well as its resistance against fouling.
Upgrading conventional trays with State-of-the-Art ones can easily add 20% catalyst activity. This activity increase can then be used to extend catalyst life or increase feed rate/heaviness, assuming extra H2 is available.
 

Catalyst cycle & feedstock optimisation

Daily optimisation normally centres on the catalyst as changes in feedstock and catalyst aging requires continuous tuning of the reactor temperature to ensure on-spec product. Using the daily & weekly feed and product analyses, the reactor average temperature can be normalised to a reference or design condition, and this normalised temperature will show the catalyst deactivation over time, allowing cycle length prediction. This normalised catalyst activity plot will also allow testing of so-called “what-if” scenarios, in which feed rate and/or severity is varied. This can be used to maximise unit margin over the cycle as a whole.

Summarising

An HDS Health Check will allow for fine-tuning of equipment in daily operation as well as for extracting maximum benefit from the catalyst load.

 
Catalyst-Intelligence is a consulting company providing independent & comprehensive advice on fixed bed catalysts to refineries and petrochemical plants. For more information on how we can help you we refer to our website: www.catalyst-intelligence.com 
 

Comments

     


  • Laurent Thouars       06-Jan-2017 11:05 PM

    Interesting article



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  • V K Kapoor       27-Jan-2017 12:52 AM

    Very nice article. Refiners attention to points raised is likely to have better techno- economic impact & improve profitability.



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  • Laurent Thouars       10-Mar-2017 10:38 AM

    Nice article. Reveals a lot of your experience. Testing



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